C3 oh's
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C3 oh's
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WebAug 11, 2015 · There are four chiral carbon atoms in the open-chain form of glucose. > The structure of glucose with its numbering is There are no internal mirror planes, so every carbon atom is different. The four chiral centres (with their attached groups) are: "C2 (OH,C1, C3, H)" "C3 (OH, C2, C4, H)" "C4 (OH, C3, C5, H)" "C5 (OH, C4, C6, H)" WebHowever, H-bond interactions involving polar residues with C3=O/C3-OH in the steroid ring appear to be responsible for positioning the substrate. These results may explain the experimental kinetic results which showed that 3-ketosterols are hydroxylated 5-10-fold faster than 3-hydroxysterols. The reaction mechanism was studied using QM:MM and ...
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Webof the C2‐OH because of its closer proximity to the anomeric center. Alternatively, the C3‐OH can selectively be protected by exploiting the slightly higher nucleo philicity of this alcohol. Selective acylation is possible, as well as regioselective alkylation. To further enhance the reactivity difference between neighboring
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